There are two ways you can make changes to the openbox menu. You can edit the menu.xml file, which is usually located with the other openbox configuration files (in ~/.config/openbox/ on Ubuntu 12.04).
There’s an easier, GUI-based way – using a program called obmenu. Once you have obmenu installed (sudo apt-get install obmenu), simply type
obmenu in a terminal. A window like will come up and allow you to change the menu that pops up with a right click on the openbox desktop.
You can find some pretty handy openbox menu.xml files on the Internet, also. I personally like the one that comes with a GNU/Linux distribution called crunchbang: Default #!crunchbang openbox menu.xml